17 Facts About Brad Pitt and Angelina Jolie’s Relationship

8) They Walked The Red Carpet As A Couple In 2006 (8 of 17)

8) They Walked The Red Carpet As A Couple In 2006 (8 of 17)

Although the world knew of their relationship, the two never walked the red carpet as a couple until December, 2006. Their first red carpet appearance together was at the NYC premiere of Jolie’s “The Good Shepherd”.